Question 6
Correct statement(s) about the compounds and is(are)
has two lone pairs of electrons on the central atom.
has a perfect octahedral geometry.
can act as a fluorinating agent.
The molecular structure of is trigonal pyramidal.
Detailed Solution
First, identify the compounds from the given reaction sequences:
- . Thus, is .
- . Thus, is .
- Complete hydrolysis of : . Thus, is .
Now evaluate the options: (A) has 8 valence electrons from . It forms 4 sigma bonds with and has 2 lone pairs ( hybridization, square planar shape). Statement is correct. (B) has 6 bond pairs and 1 lone pair on . Its geometry is distorted octahedral, not perfect octahedral. Statement is incorrect. (C) is a very strong fluorinating agent (e.g., it can fluorinate silica). Statement is correct. (D) has forming 3 double bonds with Oxygen and possesses 1 lone pair ( hybridization). Its molecular structure is trigonal pyramidal. Statement is correct.
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