Question 7

MCQHARD

A quasi-static cycle of a monoatomic ideal gas contains an isothermal process (abab), followed by an isochoric process (bcbc) and an adiabatic process (caca) as shown in the figure. The volumes of the gas are V1V_1 and V2V_2 at aa and bb, respectively. If the cycle has heat input QinQ_{\text{in}} and output QoutQ_{\text{out}}, then the efficiency of the cycle is defined as η=QinQoutQin\eta = \frac{Q_{\text{in}} - Q_{\text{out}}}{Q_{\text{in}}}. The correct statement(s) is/are: [Given: ln20.7\ln 2 \approx 0.7]

Question
(A)

If V2/V1=8V_2/V_1 = 8, the heat released in the process bcbc is smaller than the heat absorbed in the process abab.

(B)

For a given value of V2/V1V_2/V_1, η\eta does not depend on the temperature of the isothermal process.

(C)

If V2/V1=8V_2/V_1 = 8, then the temperature of the gas at aa is 4 times the temperature of the gas at cc.

(D)

If V2/V1=8V_2/V_1 = 8, then the pressure of the gas at aa is 4 times the pressure of the gas at bb.

Detailed Solution

For a monoatomic gas, γ=5/3\gamma = 5/3 and Cv=32RC_v = \frac{3}{2}R.

Process abab (Isothermal at TaT_a): Qab=nRTaln(V2/V1)Q_{ab} = nRT_a \ln(V_2/V_1). Since V2>V1V_2 > V_1, Qab>0Q_{ab} > 0 (Heat absorbed, QinQ_{\text{in}}).

Process bcbc (Isochoric at V2V_2): Qbc=nCv(TcTb)=n32R(TcTa)Q_{bc} = nC_v(T_c - T_b) = n\frac{3}{2}R(T_c - T_a). Since Tc<TaT_c < T_a, Qbc<0Q_{bc} < 0 (Heat released, Qout=QbcQ_{\text{out}} = |Q_{bc}|).

Process caca (Adiabatic): TcV2γ1=TaV1γ1    Ta/Tc=(V2/V1)2/3T_c V_2^{\gamma-1} = T_a V_1^{\gamma-1} \implies T_a/T_c = (V_2/V_1)^{2/3}.

Checking options:

(C) If V2/V1=8V_2/V_1 = 8, Ta/Tc=82/3=(23)2/3=22=4T_a/T_c = 8^{2/3} = (2^3)^{2/3} = 2^2 = 4. Thus Ta=4TcT_a = 4T_c. (C) is correct.

(B) Efficiency η=1QbcQab=132nR(TaTc)nRTaln(V2/V1)=13(1Tc/Ta)2ln(V2/V1)=13(1(V1/V2)2/3)2ln(V2/V1)\eta = 1 - \frac{|Q_{bc}|}{Q_{ab}} = 1 - \frac{\frac{3}{2}nR(T_a - T_c)}{nRT_a \ln(V_2/V_1)} = 1 - \frac{3(1 - T_c/T_a)}{2 \ln(V_2/V_1)} = 1 - \frac{3(1 - (V_1/V_2)^{2/3})}{2 \ln(V_2/V_1)}.

η\eta depends only on the ratio V2/V1V_2/V_1 and is independent of TaT_a. (B) is correct.

(A) Qbc=n32R(TaTa/4)=3234nRTa=1.125nRTa|Q_{bc}| = n\frac{3}{2}R(T_a - T_a/4) = \frac{3}{2} \cdot \frac{3}{4} nRT_a = 1.125 nRT_a.

Qab=nRTaln8=3nRTaln23×0.7nRTa=2.1nRTaQ_{ab} = nRT_a \ln 8 = 3 nRT_a \ln 2 \approx 3 \times 0.7 nRT_a = 2.1 nRT_a.

Since 1.125<2.11.125 < 2.1, heat released in bcbc is smaller than heat absorbed in abab. (A) is correct.

(D) For isothermal process abab, PaV1=PbV2    Pa/Pb=V2/V1=8P_a V_1 = P_b V_2 \implies P_a/P_b = V_2/V_1 = 8. Statement (D) says 4 times, which is incorrect.

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