Question 5

MCQHARD

Consider a hydrogen atom with vk,rk,v_k, r_k, and KkK_k denoting the velocity, orbital radius and kinetic energy of the electron in the kthk^{th} orbit, respectively. The electron undergoes a transition from the nthn^{th} orbit, emitting radiation corresponding to the Lyman series. Considering hh to be the Planck's constant and ϵ0\epsilon_0 the permittivity of the free space, the correct statement(s) is/are:

(A)

Magnitude of change in kinetic energy of electron can be expressed as h4π∣nvnrn−v1r1∣\frac{h}{4\pi} \left| \frac{nv_n}{r_n} - \frac{v_1}{r_1} \right|.

(B)

Magnitude of change in de Broglie wavelength of the electron can be expressed as e24ϵ0∣1Kn−1K1∣\frac{e^2}{4\epsilon_0} \left| \frac{1}{K_n} - \frac{1}{K_1} \right|.

(C)

Frequency of the radiation emitted can be expressed as e28πϵ0h(1r1−1rn)\frac{e^2}{8\pi\epsilon_0 h} \left( \frac{1}{r_1} - \frac{1}{r_n} \right).

(D)

Magnitude of change in total energy of the electron can be expressed as h2π∣v1r1−nvnrn∣\frac{h}{2\pi} \left| \frac{v_1}{r_1} - \frac{nv_n}{r_n} \right|.

Detailed Solution

According to Bohr's second postulate, the angular momentum of an electron in the kthk^{th} orbit is quantized: mvkrk=kh2π  ⟹  vk=kh2πmrkm v_k r_k = \frac{kh}{2\pi} \implies v_k = \frac{kh}{2\pi m r_k}

The kinetic energy of the electron is Kk=12mvk2K_k = \frac{1}{2} m v_k^2. Substituting vkv_k, we get:

Kk=12mvk(kh2Ï€mrk)=khvk4Ï€rkK_k = \frac{1}{2} m v_k \left( \frac{kh}{2\pi m r_k} \right) = \frac{kh v_k}{4\pi r_k}

For a transition from nthn^{th} orbit to the Lyman series (k=1k=1), the magnitude of change in kinetic energy is:

∣ΔK∣=∣Kn−K1∣=∣nhvn4πrn−1⋅hv14πr1∣=h4π∣nvnrn−v1r1∣|\Delta K| = |K_n - K_1| = \left| \frac{nh v_n}{4\pi r_n} - \frac{1 \cdot h v_1}{4\pi r_1} \right| = \frac{h}{4\pi} \left| \frac{n v_n}{r_n} - \frac{v_1}{r_1} \right|

Thus, option (A) is correct. For option (C), the total energy in the kthk^{th} orbit is Ek=−Kk=−e28πϵ0rkE_k = -K_k = -\frac{e^2}{8\pi\epsilon_0 r_k}.

The energy of the emitted photon is hν=∣En−E1∣=K1−Kn=e28πϵ0(1r1−1rn)h\nu = |E_n - E_1| = K_1 - K_n = \frac{e^2}{8\pi\epsilon_0} \left( \frac{1}{r_1} - \frac{1}{r_n} \right).

Therefore, ν=e28πϵ0h(1r1−1rn)\nu = \frac{e^2}{8\pi\epsilon_0 h} \left( \frac{1}{r_1} - \frac{1}{r_n} \right).

Thus, option (C) is correct.

Option (D) is incorrect because the coefficient should be h4Ï€\frac{h}{4\pi}, same as the change in kinetic energy.

Option (B) is incorrect because the de Broglie wavelength λ=hmv=h2mK\lambda = \frac{h}{mv} = \frac{h}{\sqrt{2mK}} is not linearly proportional to 1/K1/K.

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