Question 16
Reaction of Potassium Ferricyanide with Potassium Iodide
When potassium iodide is added to an aqueous solution of potassium ferricyanide, a reversible reaction is observed in which a complex is formed. In a strong acidic medium, the equilibrium shifts completely towards . Addition of zinc chloride to in a slightly acidic medium results in a sparingly soluble complex .
The number of moles of potassium iodide required to produce two moles of is
Detailed Solution
In an acidic medium, potassium ferricyanide () reacts with potassium iodide () in a redox reaction where is reduced to and is oxidized to . The balanced chemical equation is:
In this reaction, the complex is potassium ferrocyanide, . From the stoichiometry of the balanced equation, 2 moles of are required to produce 2 moles of . Therefore, the answer is 2.
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