Question 5
Among the following, the correct statement(s) for electrons in an atom is(are)
Uncertainty principle rules out the existence of definite paths for electrons.
The energy of an electron in orbital of an atom is lower than the energy of an electron that is infinitely far away from the nucleus.
According to Bohr's model, the most negative energy value for an electron is given by , which corresponds to the most stable orbit.
According to Bohr's model, the magnitude of velocity of electrons increases with increase in values of .
Detailed Solution
Option (A) is correct: Heisenberg's Uncertainty Principle states that , which prevents the determination of a precise trajectory or definite path for an electron. Option (B) is correct: The energy of an electron at infinite distance from the nucleus is taken as zero. Since the energy of a bound electron is negative ( eV), any orbital like has energy lower than zero. Option (C) is correct: In Bohr's model, the energy is inversely proportional to with a negative sign. Thus, yields the most negative value, which represents the lowest energy and most stable state (ground state). Option (D) is incorrect: According to Bohr's model, the velocity of an electron is given by , which means . Therefore, velocity decreases as increases.
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