Question 2

SCQMEDIUM

The complete hydrolysis of IClICl, ClF3ClF_3 and BrF5BrF_5, respectively, gives

(A)

IO−IO^-, ClO2−ClO_2^- and BrO3−BrO_3^-

(B)

IO3−IO_3^-, ClO2−ClO_2^- and BrO3−BrO_3^-

(C)

IO−IO^-, ClO−ClO^- and BrO2−BrO_2^-

(D)

IO3−IO_3^-, ClO4−ClO_4^- and BrO2−BrO_2^-

Detailed Solution

Hydrolysis of interhalogen compounds of the type XYnXY_n (where XX is the larger, more electropositive halogen) produces the oxyacid of XX and the halide acid of YY. The oxidation state of XX remains unchanged during hydrolysis.

  1. For IClICl (II is in +1+1 state): ICl+H2OightarrowHOI+HClICl + H_2O ightarrow HOI + HCl. The oxyanion produced is IO−IO^-.
  2. For ClF3ClF_3 (ClCl is in +3+3 state): ClF3+2H2OightarrowHClO2+3HFClF_3 + 2H_2O ightarrow HClO_2 + 3HF. The oxyanion produced is ClO2−ClO_2^-.
  3. For BrF5BrF_5 (BrBr is in +5+5 state): BrF5+3H2OightarrowHBrO3+5HFBrF_5 + 3H_2O ightarrow HBrO_3 + 5HF. The oxyanion produced is BrO3−BrO_3^-. Thus, the ions produced are IO−IO^-, ClO2−ClO_2^-, and BrO3−BrO_3^-, respectively.
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