Question 12
The monomer (X) involved in the synthesis of Nylon 6,6 gives positive carbylamine test. If 10 moles of X are analyzed using Dumas method, the amount (in grams) of nitrogen gas evolved is ______.
Use: Atomic mass of N (in amu) = 14
Detailed Solution
Nylon 6,6 is synthesized from hexamethylenediamine () and adipic acid. Hexamethylenediamine is a primary amine and thus gives a positive carbylamine test. Therefore, is hexamethylenediamine (). In Dumas method, all nitrogen in the compound is converted to gas. 1 mole of contains 2 moles of N atoms, which produce 1 mole of gas. 10 moles of will produce 10 moles of gas. Mass of gas = .
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