Question 12

NUMERICALMEDIUM

The monomer (X) involved in the synthesis of Nylon 6,6 gives positive carbylamine test. If 10 moles of X are analyzed using Dumas method, the amount (in grams) of nitrogen gas evolved is ______.

Use: Atomic mass of N (in amu) = 14

Correct Answer: 280

Detailed Solution

Nylon 6,6 is synthesized from hexamethylenediamine (H2N−(CH2)6−NH2H_2N-(CH_2)_6-NH_2) and adipic acid. Hexamethylenediamine is a primary amine and thus gives a positive carbylamine test. Therefore, XX is hexamethylenediamine (C6H16N2C_6H_{16}N_2). In Dumas method, all nitrogen in the compound is converted to N2N_2 gas. 1 mole of XX contains 2 moles of N atoms, which produce 1 mole of N2N_2 gas. 10 moles of XX will produce 10 moles of N2N_2 gas. Mass of N2N_2 gas = 10 mol×28 g mol−1=280 g10\ mol \times 28\ g\ mol^{-1} = 280\ g.

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